EPA Method 557 - Analysis of Haloacetic Acids, Dalapon, and Bromate in Drinking Water by IC-MS/MS

Instrument Type: ICMS

Haloacetic acids (HAAs) are formed as disinfection byproducts when water is chlorinated to kill bacteria. Chlorine reacts with naturally occurring organic and inorganic matter in the water, such as decaying vegetation, to produce disinfection by-products (DBPs) that include HAAs. Of the nine species of HAAs, five are currently regulated by the U.S. Environmental Protection Agency (EPA). We demonstrate a simple and sensitive IC-MS/MS method for analyzing haloacetic acids, the pesticide dalapon, and bromate in water using EPA Method 557.

AN630: EPA Method 557 – Analysis of Haloacetic Acids, Dalapon, and Bromate in Drinking Water by IC-MS/MS: HAA9

Instrument Type: ICMS

Haloacetic acids (HAAs) are formed as disinfection byproducts when municipal chlorination processes react with naturally occurring brominated and chlorinated species. Five HAAs are currently regulated, whereas four others may be included in future regulations. Here we demonstrate the determinations of 0.02 to 0.1 ng/L (ppt) HAA9 concentrations using ion chromatography separations combined with tandem MS on a triple quadrupole mass spectrometry.

AN263: Sensitive and Fast Determination of Endothall in Saline Water Sample by IC-MS/MS

Instrument Type: ICMS

Endothall, a widely used herbicide for both terrestrial and aquatic weeds, is a regulated contaminant for drinking water having a California Public Health Goal of 580 ppb. Here trace-level endothall in a saline water sample was determined directly without labor-intensive sample preparation by IC-MS-MS. The MS/MS instrument was operated in selected reaction monitoring (SRM) mode, requiring minimal sample cleanup and ensuring highly sensitive (low ppb) and selective quantitation. Isotope labeled glutaric acid (glutaric acid–d6) was used as an internal standard to ensure quantitation accuracy.

AN263: Sensitive and Fast Determination of Endothall in Surface Water Sample by IC-MS/MS

Instrument Type: ICMS

Endothall, a widely used herbicide for both terrestrial and aquatic weeds, is a regulated contaminant for drinking water with a California Public Health Goal of 580 ppb. Here trace-level endothall in a lake water sample was determined directly without labor-intensive sample preparation by IC-MS-MS. The MS/MS instrument was operated in selected reaction monitoring (SRM) mode, requiring minimal sample cleanup and ensuring highly sensitive (low ppb) and selective quantitation. Isotope labeled glutaric acid (glutaric acid–d6) was used as an internal standard to ensure quantitation accuracy.