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AN86: Determination of Trace Cations in Power Plant Waters Containing Morpholine (Method 2)

Instrument Type: IC

Morpholine and ammonium are used as additives in power plant waters. Morpholine acts as a corrosion inhibitor, whereas ammonium is used to control pH. In this matrix, it is critical to determine the presence of inorganic cation contaminants. This method uses the IonPac CS14 column to quantify trace concentrations of lithium, sodium, potassium, magnesium, and calcium in the presence of high levels of ammonium and morpholine. Acetonitrile can be added to the eluent to improve peak shape and optimize resolution for some of the cations of interest.

AN86: Determination of Trace Cations in Power Plant Waters Containing Morpholine (Method 1)

Instrument Type: IC

Morpholine and ammonium are used as additives in power plant waters. Morpholine acts as a corrosion inhibitor, whereas ammonium is used to control pH. In this matrix, it is critical to determine the presence of inorganic cation contaminants. This method uses the IonPac CS14 column to quantify trace concentrations of lithium, sodium, potassium, magnesium, and calcium in the presence of high levels of ammonium and morpholine. Acetonitrile can be added to the eluent to improve peak shape and optimize resolution for some of the cations of interest.

AN94: Determination of Trace Cations in Concentrated Acids (Phosphoric Acid) Using AutoNeutralization Pretreatment and Ion Chromatography

Instrument Type: IC

The determination of trace cationic contamination in processing acids (phosphoric, sulfuric, hydrofluoric) is important to the electronics industries to minimize corrosion. Here trace cationic contamination is determined in a 25% phosphoric acid sample. The acid sample is automatically neutralized through an electrolytic device, and then retained and concentrated onto a concentrator column. After eluting from the concentrator column, the µg/L cations are determined on an IonPac CS16 column using electrolytically generated MSA eluent and suppressed conductivity detection.